It's contra real world so its contra canon
It would be if it was, but it isn't so it isn't.
Alloys require molten metal, easily achieved with cheap fusion and electricity.
You have no idea what TL9+ alloys require. Besides, I use 'alloys' as a shorthand for all the other esoteric materials TL9+ items require.
Grav manipulation would make producing a lot of alloys a lot easier.
Indeed. Grav manipulation is the only reason why some TL9+ materials can be manufactured at all. And even then it takes huge expensive manufacturing complexes to do it.
Monocrystal alloys are likely to be a benefit of orbital manufacture and grav manipulation.
Indubitally. Not to mation all the other complicated material needed for many TL9+ items.
But seriously, there's another aspect other than plausibility and verisimilitude, namely, what do you want your PCs to be capable of? What do you want your NPCs to be capable of?
High technology has the potential to short-circuit so many plots. Nxt time you're reading a book or watching a movie or a series that is more than a couple of decades old, see how many plots would have been ruined by ubiquitous mobile phones, for example.
The one big weakness high technology has is breaking down. I can handle 3D printers that can make simple tools and replacement parts, but I really don't want my PCs to be able to toss shovel-full of ore in the manufactor's hopper and pressing a button in order to get a replacement gauss pistol or communicator or grav module.
Nor do I want space stations to be as cheap and easy to build as your suggestion implies. Possible, yes, cheap, no. That has nothing to do with how plausible I find replicators to be and everything to do with how I want my TU to function. Not to mention that many of the items on the trade lists would not really be trade items if they can be manufactured by loading a file and pressing a button.
Hans